陈真真,张立芬,李勇,杨帆,王晓华,齐永新,李彦锋

• 1:兰州大学化学化工学院
• 2:兰州大学-兰州石化公司联合实验室
• 3:中国石油兰州石化公司研究院

摘要(Abstract)：

正丁烷制顺酐Huntsman工艺于1975年首次由Monsanto公司(前Huntsman公司)实现工业化,该工艺采用了固定床列管式反应器、新型催化剂MarsV及有机溶剂吸收与精制新技术。2010年全球Huntsman工艺装置有10套左右,利用Huntsman工艺制顺酐的生产能力高达249 kt/a,其生产总能力约占整个世界顺酐总能力的38%。相比于流化床水吸收工艺,Huntsman工艺具有整体运行费用低、顺酐收率较高、产品质量较好等相对优势。然而,Huntsman工艺制顺酐也存在诸如溶剂净化、管道堵塞等问题。文中详细综述了Huntsman工艺制顺酐的流程、特点、存在的问题及其解决办法等技术进展,展望了该工艺的应用前景。

关键词(KeyWords)： 正丁烷;顺丁烯二酸酐;固定床;Huntsman工艺

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 陈真真,张立芬,李勇,杨帆,王晓华,齐永新,李彦锋

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